Solution · Wastewater and advanced oxidation

When conventional treatment falls short: advanced oxidation (POAC)

Industrial discharges with difficult organic load, colour, odour or compounds biology will not degrade. We design treatment systems with advanced oxidation processes, as the main stage or as an add-on to an existing WWTP (EDAR).

1–50 m³/h · flow-rate range Prior test on a real sample ISO 9001 · certified company
Módulo de oxidación avanzada T1 de Aguas SB instalado en una industria: bancada con cuadro de control, celdas y bombas de recirculación
T1 module installed at a food plant: control panel, electrolysis and electrocoagulation cells, cavitation line and recirculation pumps. Actual Aguas SB photograph.

Two ways to fit it in

  • As the main treatment: low-flow, high-difficulty effluents where biology is not viable.
  • As pretreatment: upstream of biology, to make biodegradable what was not.
  • As final polishing: after the WWTP (EDAR), for colour, odour and residual load before discharge.
  • As a bridge to reuse: leave the water in a state where it can be used again.
Test before sizing
The problem

The effluent almost always complies… except when it matters

Biological treatment takes most of the load, but there are fractions it will not degrade and peaks it will not absorb. That is where the problems show up.

Non-biodegradable organic load

COD that will not drop even when biology is working: the ratio of total load to biodegradable fraction shows there is matter sludge cannot eat.

Persistent colour and odour

Coloured or odorous effluent that reaches the discharge point and draws complaints and enforcement, even when other parameters are in range.

Seasonal production and peaks

Campaigns and wash-down shifts that multiply the load for weeks and destabilise a biological plant sized for the average.

Load that is penalised at discharge

When the sewer operator’s contract or your discharge conditions penalise excess organic load or solids: cut it before you discharge.

Excess sludge

The more sludge you generate, the more it costs to manage. Cutting load upstream cuts that recurring cost.

Lack of space

There is no room to enlarge ponds or reactors. You need a compact stage that works on the plant you already have.

The solution

What advanced oxidation is and why we use it

Advanced oxidation processes (POAC) generate highly reactive, short-lived oxidants inside the reactor itself. The point is not to replace conventional treatment, but to attack what it does not degrade.

Effluent characterisation

A real sample and lab analysis: organic load, solids, pH, conductivity, colour, and the flow regime (continuous, batch or campaign).

Prior conditioning

Solids separation, equalisation and pH adjustment. Oxidation works far better on water without solids and with pH under control; skipping this step makes everything that follows more expensive.

Advanced-oxidation reactor

A POAC stage sized by contact time and oxidant dose, in the configuration the test indicates. We also use electrolysis when it is better not to store reagents on site.

Polishing and outlet control

Final filtration and measurement of the control parameters to check the water leaves as agreed and to leave a running log.

Integration with the existing WWTP (EDAR)

The system is connected where it pays — before or after biology — without rebuilding the plant. In many sites it is the fastest, least invasive route.

Be careful with the figures. The performance of an advanced oxidation process depends on the water matrix, contact time and the dose applied. The simulator below shows orders of magnitude with a cycle model; it is not a commitment. First we test your sample and, on that result, we write down the achievable targets and the associated consumption.

Benefits

What you gain from an advanced-oxidation stage

It attacks what biology does not degrade

Refractory fraction, colour and odour: the POAC stage acts on exactly what stops the effluent complying.

Compact, no major civil works

A skid on a frame that slots into the existing line. It takes little space and does not force a rebuild of the WWTP.

Less sludge and lower discharge fees

Cutting load before discharge hits two recurring costs directly: sludge management and the discharge bill.

Data to evidence the discharge

Design parameters and a control log, available for your discharge permit and for your internal audit.

  • Flow rate 1 to 50 m³/h
  • Advanced oxidation (POAC)
  • Electrolysis and electrocoagulation
  • Hydrodynamic cavitation
  • Venturi aeration
  • Polishing filtration
  • WWTP (EDAR) add-on
  • Compact skid
  • ISO 9001
Estimate your case

T1 performance simulator: estimated BOD₅, COD, nitrogen and phosphorus reduction

The water does not pass the unit once: it recirculates, and each pass removes part of what is left. Enter your flow rate and lab analysis (or leave the example values) and you will see what a T1 module would do alone, what a conventional WWTP would do, and what the two do together. The rules are published below, under “How this is calculated”.

Equipment
Water to treat
Coagulant–flocculant
Oxidant for ammonium
Discharge to a sensitive area

Pre-filled values are examples. Replace them with your lab analysis; if you do not have one, the laboratory test supplies it.

Existing WWTP (for the “conventional WWTP/EDAR” bar)

Small WWTPs perform worse than large ones, especially on nitrogen and phosphorus: in the official 2023 data, 41 % of plants under 10,000 p.e. remove nitrogen, against 71 % of those between 50,000 and 150,000. The simulator weights the conventional bar a little by size, and with it the WWTP (EDAR) + T1 combination. If you do not touch the slider, size is estimated from the flow rate you enter (a conventional plant sized for that flow); if you arrive from the map, it takes that of your WWTP.

Indicative estimate

passes (cycles) through the unit
sizing
capacity used
    This is an estimate simulation, not a guaranteed result. The values come from our own calculation model, built on tests we have run with our equipment. On a real site, factors no model can capture come in: load varying through the day, temperature, conductivity, surfactants, oils, sulphides or metals, the state of pretreatment, effective contact time and how the plant is run. The real result may sit above or below the estimate. Performance is only committed by contract, on a real water analysis and, where needed, a prior pilot trial.

    What each bar means. “Inlet” is your water. “Conventional WWTP/EDAR” is what a conventional plant sized for ordinary urban load would do. “T1 only · no WWTP/EDAR” is the machine alone. “WWTP/EDAR + T1” is the T1 working on what the existing treatment leaves, which is the usual upgrade layout. The ✓/✕ marks compare the estimated outlet with the limit shown: this is guidance, not certified compliance. If you discharge to a municipal sewer, you can find the WWTP that receives your municipality’s water on the map of WWTPs in Spain.

    TREATMENT TRAIN How the T1 works RAW WATER Pre-treatment screening · grit removal grease and floatables PREREQUISITE Equalisation tank buffers the peaks T1 MODULE · CONTAINER Electro- coagulation destabilises and forms floc Electrolysis oxidises dissolved matter Hydrodynamic cavitation Venturi: breaks emulsions RECIRCULATION · n PASSES Separation flotation or settling of the floc TREATED WATER Sludge to dewatering What is removed from the water ends up here: it is a waste and must be managed. The water does not pass just once:recircula. Por eso el caudal de la máquina (m³/h) no es el caudal de la planta (m³/día): what decides the result is the number ofvueltas que da el agua por el módulo, y a partir de seis la mejora deja de ser apreciable.
    T1 treatment train: pretreatment as a precondition, a recirculation loop (the simulator’s “passes”) and a sludge line (the residue that has to be managed).
    CONFIGURATIONS Where the module fits MODE A · Intensify what is already there The proven application: the module works on what the existing plant leaves behind. INLET Pre-treatment already installed Existing WWTP / IWWTP biological treatment T1 MODULE advanced oxidation in recirculation DISCHARGE No new civil works and no larger reactor volume. It is the route with the best cost/result ratio. MODE B · Stand-alone treatment No biological stage. Only when the load is dominated by solids, grease, colloids, colour, phosphorus or metals. INLET Pre-treatment to be installed T1 MODULE electrocoagulation · electrolysis cavitation · recirculation DISCHARGE The limit of this mode is ammonium Oxidising it takes around 7.6 mg of oxidant per mg of N, which is not viable in continuous operation. With a high ammonia load the right configuration is Mode A, with a biological stage.
    Two ways to install it: as a single stage on the concentrated stream (mode A) or as polishing after the existing WWTP (mode B).
    Esquema de montaje estándar de un sistema T1: depósitos, bucle de tratamiento en recirculación, módulo con cuadro de control y conexiones numeradas
    Standard layout of a typical T1 recirculation installation (Aguas SB technical documentation).
    Detalle de las celdas de electrólisis y electrocoagulación de un módulo T1 con sus conexiones de corriente continua
    Actual detail of the electrolysis and electrocoagulation cells in the treatment loop.
    How this is calculated · what the estimate rests on

    The simulator does not apply a single percentage. That is the first thing to know, because it is what almost everyone does and it is where the disappointments come from: the same unit does not perform the same on one water as on another, and saying “it cuts 80%” without looking at the water means nothing.

    Behind it is our own model that chains several rules. We do not publish them in detail — they are part of the know-how of the system — but we do publish what they take into account, which is what lets you judge whether the number makes sense for your case.

    What the result depends on

    • Which contaminant it is. Each one is removed by a different route and goes as far as that route goes. Phosphorus precipitates very well; nitrogen depends on the form it arrives in; ammonium, simply, is not removed this way. A ceiling per parameter, not one for everything.
    • How much load it carries. The higher the inlet concentration, the less each pass removes in proportion. That is the most consistent observation from our pilots.
    • How difficult the water is. The COD to BOD₅ ratio says what share of the load is biodegradable and what share is refractory; high nitrogen and pH out of range penalise. Here is the real advantage of the system: difficult water punishes a biological treatment much harder than an electrochemical one, because ours does not need bacteria to be able to eat the matter. The simulator applies that penalty to both sides, not only to the competitor.
    • How many passes the water makes. The water does not pass once: it recirculates, and each pass removes part of what was still left. With few passes you do not reach the ceiling even if the unit is capable.
    • How many modules there are. More units do not only give more flow: they give more electrode area and more charge dose per cubic metre, and beyond a certain number they can be placed in series. That raises the ceiling, not only the capacity.

    Where the numbers come from

    From our own tests with inlet and outlet measured on the same water, not from a catalogue or from the literature. When a value is not backed by one of our tests but by the chemistry of the process, we say so in the note for that parameter: we would rather you knew now than later.

    And a decision worth explaining, because it goes against commercial instinct: the values you see include a safety margin below what we have measured. In our tests the system did more than this simulator promises. We would rather the real installation surprise you upwards.

    Where the calculation stops

    Below a certain concentration the simulator stops going down. That is not a limit of the unit: it is that the laboratory can no longer tell the difference, and we do not commit to what cannot be measured.

    The bar “WWTP (EDAR) + T1” does not add performances: it chains them. The T1 works on what the treatment you already have leaves. That is the logic of retrofit —intensify without expanding— and it is the layout in which the system gives its best cost/result ratio.

    What “conventional WWTP/EDAR” means

    A conventional WWTP sized for ordinary urban load that is receiving more than it was designed to treat. That is why its performance falls as the inlet rises. A new plant sized for that load would do better; we compare against what is installed, which is the real retrofit case.

    Precondition

    All performance figures assume pretreatment already in place: coarse screening, grit removal and grease and floatables separation. Without that no performance is demandable — sand erodes the electrodes and free grease cuts current transfer.

    Where it does not go, in our own words

    • Dissolved salts and conductivity. The system does not desalinate.
    • Sludge still has to be managed. What is taken out of the water does not vanish.

    Want the number tightened for your water? Send us the lab analysis. We do the detailed calculation, with your case in front of us, and we walk you through it.

    Size of the existing WWTP. The “conventional WWTP/EDAR” bar is weighted by the size of the plant used for comparison: small WWTPs have fewer polishing stages. According to Spain’s official 2023 report to the EU (Waterbase-UWWTD), 40 % of plants under 2,000 p.e. have tertiary treatment and 38 % declare nitrogen removal, against 81 % and 58–71 % of those over 50,000; for phosphorus, 24 % against 60 %. The official return starts at 2,000 p.e., so the smaller plants listed are few and do not stand for all that exist. The simulator weights a little for that: if you do not touch the slider, size is estimated from the flow rate (a conventional plant sized for that flow, with an allowance of 185 L per population equivalent per day, the median measured at the Spanish plants that publish their flow; on the map of Europe, each country’s own); if you arrive from the map, from the p.e. of your WWTP. It is an indicative weighting on equipment, not a measure of any particular plant’s performance, and least of all of yours.

    Bloque aparte · drinking water

    Metals in intake water: estimated removal by electrocoagulation

    Metals are mainly a drinking-water treatment (arsenic and manganese of geological origin, iron that clouds the water, lead from indoor pipework) and their values are measured in µg/L, a thousand times below discharge limits. That is why they sit in their own block and are given as a range, not as a single figure. Use the pH indicated above.

    Parametric values in RD 3/2023 (Annex I); in brackets, the transitional value and its date. A given supply may have stricter conditions: your permit prevails. The comparison with conventional drinking-water treatment uses handbook ranges, not our own tests.

    Who it’s for

    Sectors it fits

    Meat plants and slaughterhousesBlood, exudates and fat: heavily loaded effluent that varies with wash-down shifts. A sector with T1 modules in operation.
    Fish canning, fisheries and aquacultureBrines, emulsified oils and greases and fine solids; seasonal campaigns.
    Dairy and cheese plantsWhey and wash water with high organic load and detergents.
    Chemicals, soaps, inks and pharmaceuticalsColour, emulsions and poorly biodegradable compounds that biology does not degrade.
    Automotive, metal and machiningOils, cutting fluids and metals; emergency oil removal and polishing before discharge.
    Concrete plants, quarries and timberSuspended solids, pH and wash water that is worth recirculating.
    Industrial wash and service stationsDetergents, greases and hydrocarbons, with a direct interest in reusing the treated water.
    Industrial estates and collectorsThe need to cut load before handing it to the municipal sewer, under contractual limits.
    Small WWTPs and private plantsPlants that comply on average but fail at peaks: the POAC stage acts as a buffer.
    Sites with no room to expandWhen there is no room for another pond, the route is to intensify treatment, not to increase volume.
    Formats

    From the test to the final unit

    Guideline prices for T1 modules (base unit, plus VAT, approximate): T1-16 18.000 € · T1-32 25.000 € · T1-50 €37,500. Installation, pretreatment and commissioning are quoted with the study; the prior test fee is deducted from the order. Test, pilot and hire.

    Not sure what you need? Tell us what’s happening to your water in five questions and we’ll point you in the right direction.

    Start the configurator
    Conversion

    Send us your effluent and we will tell you what is possible

    The starting point is always the same: flow rate, lab analysis and which limit you need to meet. With that we propose the test and then the design.

    If you do not have a full analysis, tell us the process and the discharge point: we will say which parameters are worth measuring first so you do not spend on unnecessary tests.


      Respuesta habitual en 24–48 h laborables. Sin compromiso.

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      How we work, step by step →

      Put your effluent to the test

      One sample and one lab analysis are enough to know whether advanced oxidation solves your case and with what reach. We put it in writing.

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